Novel preparation and high electrical performance effect of Mn-doped ultra-high surface area activated carbon (USAC) as an additive for Ni hybrid capacitors

This paper reports the synthesis of various molar concentrations of manganese (Mn)-doped Ultra-High Surface area Activated Carbon (USAC) additives and their efficient use as cathode materials for supercapacitors. We synthesized the nanoparticles via a novel and facile dip-coating process and characterized them in detail by various analytical techniques. The SEM, EDAX, and XPS results showed that the Mn ions were successfully substituted on the USAC additives’ layered structure without any structural changes. The long cyclic stability of the as-prepared Mn-doped USAC additives was tested as a cathode material for supercapacitors at different current densities. The detailed experimental results showed that the Mn dopant content crucially determines the electrochemical performances of the USAC additives. Electrochemical measurements showed that the MnCEP-S600HTT with 0.10 mol% molar concentration of Mn dopant gives the best cycling performances. It delivers a discharge capacity of 262.9 mAh g^?1 after 100 cycles. Further increasing the current density to 1000 mA g^?1 allowed it to still maintain 253.6 mAh g^?1 after 200 cycles. We confirmed that the structure of Mn-doped USAC additives is an important pole to improve the structural stability and electrochemical properties.     

Permeability differences based on three-dimensional geometrical information of void spaces

In this study,the permeabilities of Berea and Otway sandstones were measured under different confining pressures,and porosity was investigated through mercury intrusion porosimetry(MIP).The total porosities of the Berea and Otway sandstones were approximately 17.4%and 25%,respectively.Pore size distributions of each sandstone were almost the same,but the pores in the Otway sandstone were slightly narrower.However,the permeability of the Otway sandstone was smaller than that of the Berea sandstone by one order of magnitude.Three-dimensional(3D)void geometry and geometrical properties of the void spaces relevant to flow were compared to obtain the relation between the permeability differences and porosities of the two sandstones.The 3D geometrical analysis using microfocus X-ray computed tomography(CT)was performed,and the pore geometries of both sandstones were compared using the 3D medial axis(3DMA)method.Pore and throat radii,pore coordination number,tortuosity,number of connecting paths,connecting path volume,and other factors were determined using 3DMA.The Otway sandstone was characterized by a small effective throat/pore radius ratio.Based on the fluid flow mechanism,the lower effective throat/pore radius ratio results in a lower permeability induced by the fluid energy loss,which means that the 3D geometrical shape of void spaces affects the permeability value.     

Novel composite membrane based on zirconium phosphate-ionic liquids for high temperature PEM fuel cells

Composite membranes composed of zirconium phosphate (ZrP) and imidazolium-based ionic liquids (IL), supported on polytetrafluoroethylene (PTFE) were prepared and evaluated for their application in proton exchange membrane fuel cells (PEM) operating at 200 °C. The experimental results reported here demonstrate that the synthesized membrane has a high proton conductivity of 0.07 S cm^?1, i.e, 70% of that reported for Nafion. Furthermore, the composite membranes possess a very high proton conductivity of 0.06 S cm^?1 when processed at 200 °C under completely anhydrous conditions. Scanning electron microscopy (SEM) images indicate the formation of very small particles, with diameters in the range of 100–300 nm, within the confined pores of PTFE. Thermogravimetric analysis (TGA) reveals a maximum of 20% weight loss up to 500 °C for the synthesized membrane. The increase in proton conductivity is attributed to the creation of multiple proton conducting paths within the membrane matrix. The IL component is acting as a proton bridge. Therefore, these membranes have potential for use in PEM fuel cells operating at temperatures around 200 °C.     

High-surface-area organic matrix tris(aza)pentacene supported platinum nanostructures as selective electrocatalyst for hydrogen oxidation/evolution reaction and suppressive for oxygen reduction reaction

Developing a Pt-based electrocatalytic material able to selectively catalyze hydrogen oxidation (HOR) while supressing oxygen reduction (ORR) is beneficial for durability of the fuel cells. Namely, degradation of carbon supported Pt particles is dramatically influenced by the unwanted ORR enrolling at the anode due to the air penetration during start-up/shut-down events. We present an organic matrix tris(aza)pentacene (TAP), which belongs to π-functional materials with ladder-like conjugated nitrogen-containing units, as the support for Pt to form a “smart” fuel cell anode able to selectively catalyze HOR and to suppress ORR. “Switching-on/off” of the composite material activity is provided by reversible reduction/oxidation of the TAP in the low potential region which provokes TAP - H_xTAP transition. Conductivity of the reduced H_xTAP enables supported Pt particles to effectively run HOR. In contrast, restricted conductivity of oxidized TAP analogue leads to the substantial drop in the ORR activity with respect to benchmark Pt/C catalyst.     

Grape skin extracts as a sustainable source of antioxidants in an oil-in-water emulsion: an alternate natural approach to synthetic antioxidants using principal component analysis

Grape (Kyoho) skin, used to retard lipid oxidation in edible oil foods, was investigated to reduce lipid oxidation in an oil-in-water (O/W) emulsion during 20 day of storage. The antioxidant efficacy of Kyoho skin extracts in O/W emulsions was determined by the measurement of secondary oxidation products. Moreover, principal component analysis (PCA) was conducted to determine similarities between emulsions treated with or without Kyoho skin extracts and standards. The data revealed that Kyoho skin extracts exhibited >93% inhibition and reported a similar p-anisidine (4.30–20.71) and TBARS (6.08–11.15 mg MDA L⁻¹) values over the standards during 20 day of storage. PCA (PCs 1 (51.83%) and 2 (18.85%)) demonstrated a similarity in the contribution of Kyoho skin extracts over the synthetic antioxidants in O/W emulsion. Overall, these findings highlighted the possibility of using Kyoho skin extracts as natural antioxidants to decrease oxidative rancidity in foods.     

Bottom-up image detection of water channel slope damages based on superpixel segmentation and support vector machine

The operation of water supply channels is threatened by the occasionally occurred slope damages. Timely detection of their occurrence is critical for the rapid enforcement of mitigation measures. However, current practices based on routine inspection and structural heath monitoring are inefficient, laborious and tend to be biased. As an attempt to address the limitations, this paper proposes a bottom-up image detection approach for slope damages, which includes four steps, i.e. superpixel segmentation, feature handcrafting, superpixel classification based on support vector machine (SVM), and slope damage recognition. The approach employs a bottom-up strategy to infer the upper-level slope condition from the classification results of individual superpixels in the bottom level. Experiments were conducted to demonstrate the effectiveness of the approach. The handcrafted feature “LBP + HSV” was demonstrated to be effective in characterizing the image features of slope damages. An SVM model with “LBP + HSV” as input can reliably identify the slope condition in superpixels. Based on the SVM model, the bottom-up strategy achieved high recognition performance, of which the overall accuracy can be up to 91.7%. The proposed approach has potential to facilitate the early and comprehensive awareness of slope damages along the entire route of water channel by the integration with unmanned aerial vehicles.     

From regional sensitivity to intra-sensitivity for parametric analysis of free-form shapes: Application to ship design

Robust Parametric Sensitivity Analysis (PSA) is a prerequisite for efficient shape optimisation via parametric modelling. A major challenge PSA has to handle is related to the fact that a parameter can be sensitive in certain local areas of the design space but become insensitive in others. Therefore, setting an applicable space for this analysis becomes a difficult task. In this paper, we introduce the concept of intra-sensitivity to identify parameters whose perturbation has a major impact on the sensitivity index of the remaining parameters. For this purpose, we firstly appeal to Active Subspace Method (ASM) and develop an ASM-based regional sensitivity analysis, which investigates parametric sensitivity in local regions of the design space and aids conducing to parameters’ intra-sensitivity. This regional analysis is applied in conjunction with a Dynamic Propagation Sampling approach, for tackling the computational complexity arising when high-dimensional problems are concerned. Once sensitive and intra-sensitive parameters are identified, then free-form features, correlated to these parameters, are evaluated using a feature saliency map built with the aid of Hausdorff distance. The so resulting methodology has been validated in the area of computer-aided ship design using two parametric modellers: the first one is a Procedural Deformation (PD) modeller which is based on T-splines and involves 24 parameters while the second one is based on Free-Form Deformation (FFD) and involves 104 parameters. The corresponding design spaces have been generated using a parent hull close to the KCS container ship and are analysed against hull’s volume of displacement and total resistance. Finally, the convergence performance of the various components of this approach is compared with state-of-the-art techniques.     

VR-Electricians: Immersive storytelling for attracting students to the electrical construction industry

Although it is projected to have significant employment growth in the electrical construction industry, there are not enough young people to join the workforce. It is indispensable for the future of work in construction to explore emerging technologies and effectively attract the younger generation to the construction industry. This paper explores the innovative use of 360-degree immersive environments powered by virtual electricians to tell success stories of the electrical construction trades on the field (VR-Electricians) and understand how such an immersive storytelling approach can attract young people to join the industry. A pretest-posttest design was used for the VR-Electricians assessment. VR-Electricians was found to significantly enhance several aspects of students’ attitude towards the electrical construction industry. VR-Electricians was also rated as a highly usable and easy-to-use system. The outcomes of this study provide construction researchers and practitioners an understanding of how immersive storytelling can be used as a powerful technology-mediated method for attracting students to their field.     

Electric transport properties of rare earth doped YbxCa1-xMnO3 ceramics (part I: Optimization of ceramic processing)

A comprehensive study was performed in order to find the effect of different calcination and sintering conditions on the physical properties of calcium manganite ceramics in dependence of temperature T and partial pressure of oxygen p(O₂). The eventual formation of oxygen vacancies during sintering was investigated and the results were confirmed by monitoring the release of oxygen using a ZrO₂ oxygen sensor. The phase transition behavior was studied using thermogravimetric analysis (TGA) in a wide range of p(O₂) ≈ 10^?1 MPa down to 10^-19 MPa at high temperatures accompanied by dilatometry- and XRD-measurements. Furthermore, the present study reveals for the first time a way for reducing and preventing crack formation that may occur during sintering. The present systematic research provides essential fundamental information before performing electrical measurements necessary in order to understand important factors about charge carriers and electrical transport mechanism.